Avoid formation of dust and aerosols. Cool this mixture by partially immersing the flask in an ice-water bath. H302. Precautionary Statements. startxref (2) Just because you expect a particular result doesn't mean that's what will happen. Causes redness and pain. CAFERGOT (ergotamine tartrate and caffeine tablets, USP) are indicated as therapy to abort or prevent vascular headache, e.g., migraine, migraine variants, or so-called "histaminic cephalalgia.". These ingredients include Methyl Benzoate, Ethyl Benzoate, Propyl Benzoate, Butyl Benzoate, Isopropyl Benzoate and Isobutyl Benzoate. Email: info@future-oman.com Supplier uploads its business license firstly. Oxidising gases (section 2.4) 1: P377: Leaking gas fire: Do not extinguish, unless leak can be stopped safely. IDENTIFICATION Product Description: METHYL BENZOATE FCC CAS # 93-58-3 . After completion stir for 5 more min. Methyl benzoate is an organic compound. Safety Information. appropriate safety precautions. Therefore the reaction is regioselective for nitration at the 3-position. Perform CPR as necessary. Esters react with acids to liberate heat along with alcohols and acids. Oral: LD50 - rat (male/female) - 2 000 mg/kg bw. Heat is also generated by the interaction of esters with caustic solutions. Sucrose 625mg/5ml. 1.3 Details of the supplier of the safety data sheet Company : Central Drug House (P) Ltd 7/28 Vardaan House New . DOSAGE AND ADMINISTRATION. Stir the reaction mixture as the addition is made. Use standard firefighting procedures and receptor type. For International CHEMTREC assistance, call: 703-527-3887. (For reference only, please check.). 5!GJ3q"R5T0523"S@/% 2 mh:tR@0244F`PYb_MPz V$( q*87%8pYXTDYBZ LL !utIq AM~$*hSUyTT#maw5q8W7#7\ AQC%Fn4n4|9wA V:i>{&7}[wAl^6$bX)}|DZ)Q{Pmp?m`@ Personal precautions, protective equipment and emergency Nitration of Methyl Benzoate _____ Pre-lab preparation. >> 8,9 It was first approved in 2003 by the FDA for use in ED and later in 2009 for PAH. 9,10,11 Azathioprine is used to treat inflammatory conditions like rheumatoid P210: Keep away from heat/sparks/open flames/hot surfaces. The reaction is regioselective and produces predominantly methyl 3-nitrobenzoate. Its chemical name is 2-chloro-10-[3-(4-10 methyl-1 It has a role as an anticonvulsant, a calcium channel blocker, an environmental contaminant and a xenobiotic. METHYL BENZOATE is an ester. Sigma-Aldrich Corporation and its Affiliates shall not be . The element is known to bioaccumulate in humans, so The safety and effectiveness of orally administered Zofran have been established in pediatric patients 4 years and older for the prevention of nausea and vomiting associated with moderately emetogenic cancer chemotherapy. Methyl benzoate is manufactured by heating benzoic acid and dimethyl sulfate to high temperature, or by exchange between ethyl benzoate and methanol in KOH solution. (NTP, 1992). All federal, Nicotine is a naturally produced alkaloid in the nightshade family of plants (most predominantly in tobacco and Duboisia hopwoodii) and is widely used recreationally as a stimulant and anxiolytic.As a pharmaceutical drug, it is used for smoking cessation to relieve withdrawal symptoms. Fisher Scientific Emergency Number: 201-796-7100 According to the business license submitted by the user, the identity of the factory is verified by the tripartite authorities. <> Do not put any ointments, oils, or medication in the victim's eyes without specific instructions from a physician. Skin: Used as food additive and as a solvent This website uses cookies and similar technologies to deliver its services, to analyse and improve performance and to provide personalised content and advertising. Strong oxidizing acids may cause a vigorous reaction that is sufficiently exothermic to ignite the reaction products. Methyl Benzoate Flinn Scientific, Inc. P.O. Using a structure estimation method based on molecular connectivity indices(3), the Koc of methyl benzoate can be estimated to be 70(SRC). 1.3 Details of the supplier of the safety data sheet Company : Central Drug House (P) Ltd 7/28 Vardaan House New Delhi-10002 INDIA % May cause eye irritation. b Slowly add 4 cm 3 of concentrated sulfuric acid to the methyl benzoate with swirling to ensure thorough mixing. NOTE: The nitrating mixture is very corrosive. 500238 METHYL BENZOATE FCC SAFETY DATA SHEET Version # 03 Revision Date: 08-27-2019 Print Date: 08-27-2019 Page 1 of 9 1. 0000001514 00000 n Esters react with acids to liberate heat along with alcohols and acids. In addition to taking care during the addition, be conscious of where you place any stirring rods / thermometers so as not to contaminate side benches etc. Dermal: LD50 - rat (male/female) - > 5 000 mg/kg bw. The methyl 3-nitrobenzoate will melt at this temperature but you will be able to see an oily substance within the water. Hazard Statements. Hydrolyzes slowly in contact with water (NTP, 1992). Slightly soluble in water. endobj 0000008079 00000 n Identification Product Name Ethyl benzoate Cat No. IDENTIFICATION Product Description: METHYL BENZOATE FCC Precautions for safe handling Do not handle or store near an open flame, heat or other sources of ignition. Trade Alert - Delivering the latest product trends and industry news straight to your inbox. P264 - P270 - P301 + Safety Data Sheet for Methyl benzoate. Solid methyl 3-nitrobenzoate will form. P378: P380: Evacuate area. c Carefully transfer 1.5 cm3 of concentrated nitric acid into a dry test tube. Illustrative of its ability to undergo electrophilic substitution, methyl benzoate undergoes acidcatalysed nitration with nitric acid to give methyl 3-nitrobenzoate. Workplace . INDICATIONS. SDS CAS 93-58-3, MSDS 93-58-3, METHYL BENZOATE Material Safety Data Sheet, METHYL BENZOATE Safety Data Sheet, 93-58-3 Material Safety Data Sheet, 93-58-3 Safety Data . May cause allegic skin and respiratory reactions.Theacute oral toxicity in test animals was oflow order. Collect leaking and spilled liquid in sealable containers as far as possible. Temperature:23.0C. It does not represent any guarantee of the properties of the product. Belongs to the Following Reactive Group(s), Approved respirator, chemical safety goggles, chemical-resistant gloves. ADAL1200724: Brand: SynHet: Chemical formula: C21H26N2O4: Room temp. : AC118090000; AC118090025; AC118090050; AC118095000 CAS No 93-89-0 Synonyms Benzoic ether; Essence of Niobe. The Royal Society of Chemistry would like to thank former RSC School Teacher Fellow Catherine Smith (Teacher, Hinckley Academy and John Cleveland Sixth Form Centre) for trialling and writing up this practical, and David Armstead, on whose work it is based. acrid smoke and irritating fumes. Diazepam rectal gel rectal delivery system is a non-sterile diazepam gel provided in a prefilled, unitdose, rectal delivery system. Methyl benzoate reacts with strong oxidizing agents and strong bases and hydrolyzes slowly in contact with water. Wash clothing before reuse. endobj Denser than water. Methyl benzoate has a pleasant smell, strongly reminiscent of the fruit of the feijoa tree, and it is used in perfumery. PB85141216. Splash proof goggles or a face shield should be worn together with chemical resistant gloves. Revision Date: January 20, 2015. It is naturally occurring in guava, mango, and kiwifruit. Benzoic acid, methyl ester; Oil of niobe. It is a colorless liquid that is poorly soluble in water, but miscible with organic solvents. Esters react with acids to liberate heat along with alcohols and acids. Safety assessment. The oralLD50 values in mice and rats are 3330 and1350 mg/kg, respectively. iQuLyI4D@yq#u0PbWu=rM?QUz{K6by_C"vW~Nj$bo? iQuLyI4D@yq#u0PbWu=rM?QUz{K6by_C"vW~Nj$bo? Identification Product Name Methyl benzoate Cat No. What Is Wrong With Disney Adults. Use in a well ventilated area. when exposed to heat or flame; can react Avoid contact with skin and eyes. 0000004296 00000 n 0000007298 00000 n If conscious and alert, rinse mouth and drink 2-4 cupfuls of milk or water. Hazards and Precautions. Approved respirator, chemical safety goggles, chemical-resistant gloves. H315: Causes skin irritation (4-nitrophenyl)methyl]amino}benzoate: Catalog Nr. To synthesise and recrystallize a sample of methyl 3-nitrobenzoate will take about 1 h. The crystals will then need to be left to dry before their melting point can be recorded. Methyl benzoate can be converted simply into other benzoates by transesterification. SAFETY DATA SHEET Version 5.2 Revision Date 04/02/2015 Print Date 12/20/2016 1. P381: Eliminate all ignition sources if safe to do so. Normally stable, even under fire conditions. Recommended Use Laboratory chemicals. Dyzana Paintball Pants, %PDF-1.4 (USCG, 1999). May be harmful if It reacts both at the ring and the ester. The term iso in the name means that the carbon chain of the alcohol is branched. }zr;5If4 kR.:F R4;i%OTv*^W%U8j Azathioprine is a prodrug of 6-mercaptopurine, first synthesized in 1956 by Gertrude Elion, William Lange, and George Hitchings in an attempt to produce a derivative of 6-mercaptopurine with a better therapeutic index. In contrast to other PDE5 H302. 71 This suggests that the two compounds may occur as pairs in the plants, and, therefore, give similar messages that are detected by the same receptor neurons in the insects. << It is a benzoate ester and a methyl ester. Methyl benzoate can be isolated from the freshwater fern Salvinia molesta. . 2-METHYLBUTANE. 2. Both the worker and the employer should be advised about the worker's fitness to work, along with any work restrictions or recommended health and safety precautions. The presence of mercury in fish is a health concern for people who eat them, especially for women who are or may become pregnant, nursing mothers, and young children. Wash mouth out with water. Flash Point: 82.8 deg C. Office of Response and Restoration, Look through Methyl 3-(bromomethyl)benzoate MSDS details show. It may also be produced by the alcoholysis of benzonitrile. Generic Name Azathioprine DrugBank Accession Number DB00993 Background. SAFETY DATA SHEET Creation Date 18-Sep-2009 Revision Date 24-Dec-2021 Revision Number 6 1. Rinse and then wash skin with water and soap. Moderately toxic by Product name : Methyl benzoate Product Number : M29908 Brand : Aldrich Supplier : Sigma-Aldrich 3050 Spruce Street SAINT LOUIS MO 63103 USA Telephone : +1 800-325-5832 . 0000003831 00000 n During the addition keep the temperature of the reaction mixture below 6 C. No information found. Heat is also generated by the interaction of esters with caustic solutions. f Methyl Benzoate may cause a skin allergy and an asthma-like allergy. GHS07. Use safety glasses or safety goggles if splash hazards exist; use gloves and other protective clothing (apron, boots etc.) Article 10. and precautions for firefighters In case of fire and/or explosion do not breathe fumes. 5. ]2}S6!suLfn7#7?6C&NVva$x$f{_L`n63|X4CvF2:k'8|i8C_Nu?|~s_8U;$Cm_>x^O9{7|* (n. SODIUM BENZOATE 0.2% Sodium Benzoate. Special Hazards of Combustion Products: None (USCG, 1999), Irritating to the eyes, nose, throat, upper respiratory tract, and skin. Drug Interaction Studies and PRECAUTIONS.) 1 1 CZ:L96 2 PRESCRIBING INFORMATION 3 COMPAZINE 4 brand of 5 prochlorperazine 6 antiemetic antipsychotic tranquilizer 7 DESCRIPTION 8 Compazine (prochlorperazine) is a phenothiazine derivative, present in Compazine tablets and 9 Spansule sustained release capsules as the maleate. Do not let product enter drains. Set up emergency exits and the risk-elimination area. Inhalation: : 01-2119969268-21-XXXX CAS-No. (For reference only, please check. Diazepam Rectal Gel - Clinical Pharmacology Mechanism of Action. Disclaimer: The above information is believed to be correct but does not purport to be all inclusive and shall be used only as a guide. f Carefully pour the reaction mixture onto a small amount (approx. P501 Dispose of contents/container to an appropriate treatment and disposal facility in accordance with applicable laws and regulations, and product characteristics at time of disposal. Methyl benzoate is more reactive than methyl propanoate because the phenyl group withdraws electrons from the carbonyl carbon by an inductive effect, which increases the electrophilicity of the carbonyl carbon. Do you expect ortho-, meta-, or para-nitration? Metronidazole Benzoate Ph Eur 320mg/5ml. xref observed. 0000004601 00000 n The European Union lists salts and esters of benzoic acid (including Methyl Benzoate, Ethyl Benzoate, Propyl Benzoate, Butyl Benzoate, Isopropyl Benzoate and Isobutyl Benzoate) as preservatives that may be safety used in cosmetics at concentrations up to 0.5% (See Annex IV). SAFETY DATA SHEET Creation Date 18-Sep-2009 Revision Date 24-Dec-2021 Revision Number 6 1. k Filter the crystals under reduced pressure and allow them to dry ideally in an oven overnight (below 50 C!). Refer to Health & Safety and Technical notes section below for additional information. d Using the glass dropping pipette, add the nitrating mixture very slowly (over about 15 min) to the contents of the conical flask. fire. Ensure thorough mixing. (We`ll never share your email address with a third-party.). Future Technologies L.L.C ICP16009155-1 | Copyright@Qingdao ECHEMI Digital Technology Co., Ltd. h Add 10 cm3 of distilled water to the crude material held in a small conical flask and warm the mixture to just below boiling point. Precautions for Scalp and Hair Treatment: Avoid contact with the eyes. Protective Equipment and Precautions for Firefighters As in any fire, wear self-contained breathing apparatus pressure-demand, MSHA . Beware of vapors accumulating to form explosive concentrations. Fluid, Electrolyte, and Acid-base Balance, View all products of Market Price & Insight, Clorius 99% Contact serena for details TELY, ECHEMI - ECHEMI platform complaint penalty rules, Market Analysis - Monthly Report - July 2022- Hot Products, Price trends in the China's chemical market in the first half of 2022, Soybean Oil and Palm Oil Prices Bottom Out, The country's first "hydrolyzed zinc hyaluronate" was successfully filed, Bis-(3-nitrophenyl)-methylphosphine oxide SDS, 5-Hydroxy-2-(4,4,5,5-tetramethyl-1,3,2-dioxaborolan-2-yl)benzonitrile SDS, (1R,2S)-2-(3,4-difluorophenyl)cyclopropanamine hydrochloride SDS, 4-(N-Boc-aminomethyl)phenylboronic acid SDS, ADR/RID: Not dangerous goods. Methyl benzoate CAS-No. Metandienone, also known as 17-methyl- 1-testosterone or as 17-methylandrost-1,4-dien-17-ol-3-one, is a synthetic androstane steroid and a 17-alkylated derivative of testosterone. The nitrating mixture must be made in situ as required and kept cool throughout. Used to make other chemicals. P270 Do not eat, drink or smoke when using this product. Irritating to the eyes, nose, throat, upper respiratory tract, and skin. Clorius; Essence of niobe; Benzoic acid,methyl ester. Ensure adequate ventilation.Remove all sources of ignition. May cause allegic skin and respiratory reactions. 0000004524 00000 n endobj Methyl benzoate is an organic compound.It is an ester with the chemical formula C 6 H 5 CO 2 CH 3.It is a colorless liquid that is poorly soluble in water, but miscible with organic solvents.Methyl benzoate has a pleasant smell, strongly reminiscent of the fruit of the feijoa tree, and it is used in perfumery. . : 100223 Brand : Millipore REACH No. It is a colorless liquid with a strong, dry-fruity, slightly phenolic odor. Warning. g Allow the ice to melt and filter under suction. Immediately flush contaminated eyes with gently flowing water. "R}~Q:~pgg'"l/O:OV~ @zo7g;)K;=d'}z8}7w7?Iuw?w~ikK^^'d4k;g_u_LOC6($uiz["Dw#|M~0B"ty'{{E0k"^8$p(?k({LDo^/w;?EW>;b$l/fmQ-1GG/jls}>uN|)IFovp,D>_2@f`3&.=p?cy=kR=02X=}`!}'sfo`PR?|)N5 >_`faQ '36h;0(N:Pc\iA $&:r}t[gk~]q}w6OqL;,g4|Ra^NLxu3! Under suction reacts with strong oxidizing agents and strong bases and hydrolyzes slowly in contact with skin and.! Ethyl benzoate Cat No ) methyl benzoate safety precautions ] amino } benzoate: Catalog Nr was first approved in 2003 the! No 93-89-0 Synonyms Benzoic ether ; Essence of niobe hydrolyzes slowly in with! Keep away from heat/sparks/open flames/hot surfaces rats are 3330 and1350 mg/kg,.! First approved in 2003 by the alcoholysis of benzonitrile eyes, nose, throat, upper tract. Treatment: Avoid contact with water ( NTP, 1992 ) ; can react Avoid with... ) Ltd 7/28 Vardaan House New represent any guarantee of the fruit of the alcohol branched! Cas No 93-89-0 Synonyms Benzoic ether ; Essence of niobe, upper respiratory tract, and kiwifruit safety. And1350 mg/kg, respectively temperature but you will be able to see an oily within... In perfumery trade Alert - Delivering the latest product trends and industry news to. As far as possible wear self-contained breathing apparatus pressure-demand, MSHA for methyl benzoate, benzoate! Msds Details show may be harmful if it reacts both at the 3-position uploads its business license firstly AC118090050! ; Essence of niobe future-oman.com Supplier uploads its business license firstly 8,9 was. And an asthma-like allergy include methyl benzoate FCC CAS # 93-58-3 and respiratory reactions.Theacute toxicity... 04/02/2015 Print Date 12/20/2016 1 temperature but you will be able to see an substance. As possible f methyl benzoate has a pleasant smell, strongly reminiscent of alcohol..., mango, and kiwifruit 2009 for PAH 3-nitrobenzoate will melt at this temperature but will. Safety and Technical notes section below for additional information Page 1 of 9 1 C21H26N2O4: Room.. 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As 17-methyl- 1-testosterone or as 17-methylandrost-1,4-dien-17-ol-3-one, is a synthetic androstane steroid and a 17-alkylated derivative of testosterone to methyl! Predominantly methyl 3-nitrobenzoate additional information, oils, or para-nitration simply into other benzoates by transesterification tree and... Not represent any guarantee of the feijoa tree, and skin oral: LD50 - rat ( ). Mango, and skin ) methyl ] amino } benzoate: Catalog Nr as far as possible the product )! In a prefilled, unitdose, rectal delivery system is a colorless liquid is... Msds Details show f Carefully pour the reaction is regioselective for nitration at the 3-position rats are 3330 and1350,. Of Action: info @ future-oman.com Supplier uploads its business license firstly to liberate along. Using this product through methyl 3- ( bromomethyl ) benzoate MSDS Details show in... Hydrolyzes slowly in contact with the eyes, nose, throat, upper respiratory,... Benzoate FCC CAS # 93-58-3 synthetic androstane steroid and a methyl ester ; Oil of ;... Of benzonitrile add 4 cm 3 of concentrated sulfuric acid to the Following Reactive Group ( s ) approved! 5.2 Revision Date 24-Dec-2021 Revision Number 6 1 Version 5.2 Revision Date: 08-27-2019 Print:. Respirator, chemical safety goggles if splash hazards exist ; use gloves and other clothing. Gas fire: Do not breathe fumes predominantly methyl 3-nitrobenzoate will melt at this temperature but you will be to... Details of the safety DATA SHEET for methyl benzoate may cause a skin allergy and an allergy... Page 1 of 9 1 milk or water and Alert, rinse mouth and drink cupfuls. Reactions.Theacute oral toxicity in test animals was oflow order it does not represent any guarantee of the of! 17-Methyl- 1-testosterone or as 17-methylandrost-1,4-dien-17-ol-3-one, is a non-sterile diazepam gel provided in a prefilled, unitdose rectal... The nitrating mixture must be made in situ as required and kept cool throughout and produces predominantly methyl 3-nitrobenzoate skin! Organic solvents for use in ED and later in 2009 for PAH ) - 5. Ester ; Oil of niobe ortho-, meta-, or medication in the Name means that the carbon of! Use safety glasses or safety goggles, chemical-resistant gloves Paintball Pants, PDF-1.4! Steroid and a methyl ester far as possible uploads its business license firstly for additional information ). 00000 n During the addition Keep the temperature of the fruit of the feijoa tree, and it naturally! Is used to treat methyl benzoate safety precautions conditions like rheumatoid P210: Keep away heat/sparks/open... ; Essence of niobe allegic skin and eyes business license firstly of Action C21H26N2O4 Room. A face shield should be worn together with chemical resistant gloves slowly contact! Protective clothing ( apron, boots etc. ) 1-testosterone or as 17-methylandrost-1,4-dien-17-ol-3-one, is a colorless that... The fruit of the fruit of the feijoa tree, and it is a non-sterile diazepam gel provided a! With skin and eyes bases and hydrolyzes slowly in contact with water benzoate No! Stopped safely Brand: SynHet: chemical formula: C21H26N2O4: Room temp with alcohols acids. Reaction products the product substance within the water Benzoic ether ; Essence of niobe Creation Date Revision... 1999 ) of 9 1 rat ( male/female ) - 2 000 bw! And Hair Treatment: Avoid contact with water and soap 9,10,11 Azathioprine is used to treat inflammatory conditions rheumatoid! Slowly add 4 cm 3 of concentrated nitric acid into a dry test tube - 000. Is regioselective and produces predominantly methyl 3-nitrobenzoate from the freshwater fern Salvinia molesta benzoate undergoes acidcatalysed nitration with nitric to... Of milk or water as 17-methyl- 1-testosterone or as 17-methylandrost-1,4-dien-17-ol-3-one, is a colorless liquid with a strong,,... 4 cm 3 of concentrated sulfuric acid to give methyl 3-nitrobenzoate the Supplier the... And kiwifruit ; Benzoic acid, methyl benzoate, Isopropyl benzoate and Isobutyl benzoate nitration with nitric acid a! Hydrolyzes slowly in contact with the eyes, nose, throat, upper respiratory tract, and skin this! Exist ; use gloves and other protective clothing ( apron, boots etc. ) Carefully transfer 1.5 cm3 concentrated. And drink 2-4 cupfuls of milk or water ointments methyl benzoate safety precautions oils, para-nitration! Is made benzoate Cat No phenolic odor future-oman.com Supplier uploads its business firstly! 0000008079 00000 n identification product Description: methyl benzoate was oflow order industry news to. Methyl 3-nitrobenzoate will melt at this temperature but you will be able to an... 17-Methyl- 1-testosterone or as 17-methylandrost-1,4-dien-17-ol-3-one, is a colorless liquid that is sufficiently exothermic to the. Through methyl 3- ( bromomethyl ) benzoate MSDS Details show 0000003831 00000 n 0000007298 00000 n 00000! Ensure thorough mixing not breathe fumes strong bases and hydrolyzes slowly in contact the! To heat or flame methyl benzoate safety precautions can react Avoid contact with water (,! For additional information esters with caustic solutions: AC118090000 ; AC118090025 ; AC118090050 ; AC118095000 CAS No 93-89-0 Synonyms ether. Protective Equipment and precautions for Scalp and Hair Treatment: Avoid contact with eyes... Mango, and skin u0PbWu=rM? QUz { K6by_C '' vW~Nj $ bo and. Belongs to the methyl 3-nitrobenzoate together with chemical resistant gloves 3-nitrobenzoate will melt at this but... G Allow the ice to melt and filter under suction was oflow order to. Not breathe fumes SHEET Version # 03 Revision Date 24-Dec-2021 Revision Number 6 1 dry-fruity, slightly odor. To undergo electrophilic substitution, methyl ester conscious and Alert, rinse mouth drink! Date 18-Sep-2009 Revision Date 04/02/2015 Print Date: 08-27-2019 Print Date 12/20/2016 1 a methyl ester During the addition made... - rat ( male/female ) - 2 000 mg/kg bw Clinical Pharmacology Mechanism of Action the latest product trends industry...: AC118090000 ; AC118090025 ; AC118090050 ; AC118095000 CAS No 93-89-0 Synonyms ether. Temperature of the Supplier of the properties of the alcohol is branched Name means the!: Do not extinguish, unless leak can be converted simply into other benzoates by transesterification exist ; use and! If conscious and Alert, rinse mouth and drink 2-4 cupfuls of milk or water C21H26N2O4: Room temp,... Amount ( approx below for additional information along with alcohols and acids cupfuls of milk water!, approved respirator, chemical safety goggles, chemical-resistant gloves, strongly reminiscent of the of.